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Science 5 September 2008:
Vol. 321. no. 5894, pp. 1328 - 1331
DOI: 10.1126/science.1159178
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Reports

Experimental Test of Self-Shielding in Vacuum Ultraviolet Photodissociation of CO

Subrata Chakraborty,1 Musahid Ahmed,2 Teresa L. Jackson,1 Mark H. Thiemens1*

Self-shielding of carbon monoxide (CO) within the nebular disk has been proposed as the source of isotopically anomalous oxygen in the solar reservoir and the source of meteoritic oxygen isotopic compositions. A series of CO photodissociation experiments at the Advanced Light Source show that vacuum ultraviolet (VUV) photodissociation of CO produces large wavelength-dependent isotopic fractionation. An anomalously enriched atomic oxygen reservoir can thus be generated through CO photodissociation without self-shielding. In the presence of optical self-shielding of VUV light, the fractionation associated with CO dissociation dominates over self-shielding. These results indicate the potential role of photochemistry in early solar system formation and may help in the understanding of oxygen isotopic variations in Genesis solar-wind samples.

1 Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093–0356, USA.
2 Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA.

* To whom correspondence should be addressed. E-mail: mthiemens{at}ucsd.edu

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THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Comment on "Experimental Test of Self-Shielding in Vacuum Ultraviolet Photodissociation of CO".
J. R. Lyons, R. S. Lewis, and R. N. Clayton (2009)
Science 324, 1516
   Abstract »    Full Text »    PDF »
Comment on "Experimental Test of Self-Shielding in Vacuum Ultraviolet Photodissociation of CO".
S. R. Federman and E. D. Young (2009)
Science 324, 1516
   Abstract »    Full Text »    PDF »
Comment on "Experimental Test of Self-Shielding in Vacuum Ultraviolet Photodissociation of CO".
Q.-Z. Yin, X. Shi, C. Chang, and C.-Y. Ng (2009)
Science 324, 1516
   Abstract »    Full Text »    PDF »
Response to Comments on "Experimental Test of Self-Shielding in Vacuum Ultraviolet Photodissociation of CO".
S. Chakraborty, M. Ahmed, T. L. Jackson, and M. H. Thiemens (2009)
Science 324, 1516
   Abstract »    Full Text »    PDF »


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